Fractional distillation of crude oil
Crude oil heated; vapour rises; different fractions condense at different heights.
Crude oil (also called petroleum) is a thick, dark, complex mixture of hydrocarbons. Refining splits it into useful fractions using fractional distillation.
How it works:
- Crude oil is heated in a furnace to about 350-400 °C — most of it vaporises.
- Vapour rises up a tall column (the fractionating column).
- The column is HOT at the bottom and COOLER at the top.
- As vapour rises, it gradually cools. Each fraction condenses out at a specific height where the temperature matches its boiling point range.
Main fractions, from top of column (lowest BP) to bottom (highest BP):
| Fraction | Carbon range | Typical use |
|---|---|---|
| Refinery gas | C1-C4 | Heating, cooking gas (LPG) |
| Petrol (gasoline) | C5-C10 | Car engines |
| Naphtha | C7-C14 | Petrochemical feedstock |
| Kerosene | C10-C16 | Jet fuel, lamp oil, heating |
| Diesel (gas oil) | C12-C20 | Diesel engines, trucks, trains |
| Fuel oil | C20-C40 | Ship fuel, factory heating |
| Bitumen (residue) | C40+ | Road surfaces, roofing |
Properties shift gradually with chain length:
- Longer chains → higher BP, more viscous (thick), less volatile, less flammable, darker colour.
- Shorter chains → lower BP, runny, very volatile, easy to ignite.
This is why petrol is a runny liquid that ignites easily (so engines start cold) but bitumen is a thick black tar.
- Crude oil = complex mixture of hydrocarbons.
- Fractional distillation separates by boiling point.
- Top of column: short chains (refinery gas, petrol). Bottom: long chains (bitumen).
- Properties (BP, viscosity, volatility) change predictably with chain length.