What addition polymerisation is
Alkene monomers add together — the C=C opens to make a long saturated chain, with no by-product.
Addition polymerisation is the joining of many small alkene (unsaturated) monomers into a single long-chain polymer, with no other product formed (unlike condensation polymerisation, which loses a small molecule).
The C=C double bond opens up and the carbons bond to neighbouring monomers, forming the polymer backbone:
Examples:
- Ethene → poly(ethene): .
- Chloroethene (CH₂=CHCl) → poly(chloroethene), PVC: .
- Propene → poly(propene): .
- Many alkene monomers → one polymer, no by-product.
- C=C opens to form the backbone.
- Ethene → poly(ethene); chloroethene → PVC.