Atomic number and mass number (spec 1.16)
Z = protons (defines the element); A = protons + neutrons.
Every atom has a tiny central nucleus containing protons and neutrons, with electrons in shells around it. Two numbers describe the make-up of that atom.
- Atomic number, Z = the number of protons in the nucleus. Z is what makes an element that element — every carbon atom has 6 protons, every sodium atom has 11 protons.
- Mass number, A = the total number of protons + neutrons (the heavy particles in the nucleus). Electrons are far too light to count here.
Because A counts the protons and the neutrons, you can always find the number of neutrons by subtracting:
number of neutrons = A − Z
Nuclide (isotope) notation. Atoms are written with the mass number on top and the atomic number on the bottom, in front of the chemical symbol — for example ²³₁₁Na (sodium-23). Both numbers go on the left of the symbol.
Mark-scheme tip. If you write the line "neutrons = A − Z" before you do the arithmetic, you secure the method mark even if the final number is wrong (error-carried-forward). Always show the subtraction.
- Z = number of protons (the bottom, smaller number).
- A = number of protons + neutrons (the top, larger number).
- Neutrons = A − Z.
- Z defines the element — same element always has the same Z.
See the full worked example for key terms in atomic structure →