Air pollution: pollutants, smog and temperature inversion
Urban air pollution comes from vehicle exhausts, industry and domestic burning, releasing particulates, NOx, SO2 and CO; it produces classic industrial smog or photochemical smog, and temperature inversion can trap these pollutants over a city.
The first job in 12.3 is to identify the main TYPES of urban air pollution precisely, name the pollutants, and explain how smog forms — because air pollution is the headline urban problem.
The main sources and pollutants.
- Vehicle exhausts (the largest source in most cities) emit nitrogen oxides (NOx), carbon monoxide (CO), particulate matter (PM2.5 and PM10) and unburnt hydrocarbons (VOCs).
- Industry (factories, power stations) emits sulfur dioxide (SO2), NOx and particulates, especially where coal or heavy oil is burnt.
- Domestic burning of coal, wood and waste for heating and cooking adds smoke and particulates — a major source in poorer cities.
Two kinds of smog.
- Classic / industrial ('London') smog is a mix of smoke and sulfur dioxide trapped in fog, produced by burning coal in cool, damp, still conditions. The London 'Great Smog' of 1952 killed an estimated 4,000+ people and led to the UK Clean Air Acts.
- Photochemical smog is the modern type: in strong sunlight, NOx and VOCs from traffic react to form ground-level ozone (O3) and a brown haze. It is worst in warm, sunny, car-dominated cities — Los Angeles, Mexico City, Beijing and Delhi are the classic cases.
Temperature inversion — the trap.
- Normally air cools with height, so warm polluted surface air rises and disperses. In a temperature inversion, a layer of warm air sits ABOVE cooler surface air, acting as a lid: the cool surface air (and its pollutants) cannot rise through it, so smog accumulates over the city — especially in basins like Los Angeles and Mexico City where surrounding hills also trap the air.
Acid deposition.
- SO2 and NOx react with water in the atmosphere to form acids that fall as acid rain (acid deposition), damaging buildings, soils, lakes and vegetation downwind.
| Pollutant | Main urban source | Main effect |
|---|---|---|
| Particulates (PM2.5 / PM10) | Vehicle exhausts, burning, construction | Penetrate lungs → respiratory/cardiovascular disease |
| Nitrogen oxides (NOx) | Vehicle exhausts, power stations | Photochemical smog; acid rain; lung irritation |
| Sulfur dioxide (SO2) | Coal/oil burning, industry | Industrial smog; acid rain; respiratory harm |
| Carbon monoxide (CO) | Incomplete combustion in engines | Reduces oxygen carried by blood; toxic |
| Ground-level ozone (O3) | Formed from NOx + VOCs + sunlight | Photochemical smog; lung damage |
The take-home for 12.3.1: name the pollutants and their sources, distinguish INDUSTRIAL smog (smoke + SO2 in fog) from PHOTOCHEMICAL smog (NOx + sunlight → ozone), and explain how temperature inversion traps both over a city.
- Sources: vehicle exhausts (NOx, CO, PM, VOCs), industry (SO2, NOx, PM) and domestic burning (smoke, PM).
- Industrial ('London') smog = smoke + SO2 trapped in fog from coal burning — London Great Smog 1952 (4,000+ deaths).
- Photochemical smog = NOx + VOCs + strong sunlight → ground-level ozone (Los Angeles, Mexico City, Beijing, Delhi).
- Temperature inversion = warm air lid sitting ABOVE cool surface air, trapping pollutants so smog builds up.
- Basins ringed by hills (Los Angeles, Mexico City) worsen the trapping effect of inversions.
- SO2 and NOx form acid deposition (acid rain), damaging buildings, soils, lakes and vegetation.