Atmospheric moisture: phase changes and latent heat
Water moves between vapour, liquid and ice by five phase changes — and each one moves latent heat into or out of the air.
Water is the only substance in the atmosphere that exists in all three states — gas (water vapour), liquid (water droplets) and solid (ice) — at everyday temperatures. Moving between them is what drives weather, because each change of state involves an exchange of latent heat ('hidden' heat that changes the state of water without changing its temperature).
There are five phase changes you must name:
| Phase change | Direction | Latent heat | Effect on the air |
|---|---|---|---|
| Evaporation | liquid → gas | absorbed | cools the surroundings |
| Condensation | gas → liquid | released | warms the surrounding air |
| Freezing | liquid → solid | released | warms the surrounding air |
| Melting | solid → liquid | absorbed | cools the surroundings |
| Sublimation | solid ⇆ gas (directly) | absorbed (ice→vapour) / released (vapour→ice) | — |
Why latent heat matters: when water evaporates from a warm ocean it takes energy with it, so that energy is stored in the vapour. When that vapour later condenses high in the atmosphere, the latent heat is released, warming the surrounding air, making it more buoyant and driving it to rise still further. This is the engine of convectional rainfall and of tropical storms — so latent heat is not a side note; it is a cause.
Three terms to define precisely:
- Humidity — the amount of water vapour held in the air (absolute humidity is the mass of vapour per volume of air).
- Relative humidity (%) — how much vapour the air holds compared with the maximum it could hold at that temperature. Warm air can hold more vapour than cold air, so as air cools its relative humidity rises towards 100 %.
- Saturation / dew point — air is saturated when its relative humidity reaches 100 %. The temperature at which this happens is the dew point. Cool the air below its dew point and the surplus vapour must condense into water droplets.
- Five phase changes: evaporation, condensation, freezing, melting, sublimation (ice ⇆ vapour directly).
- Latent heat is ABSORBED on evaporation and melting (cooling); RELEASED on condensation and freezing (warming).
- Released latent heat warms the air, making it more buoyant — the driver of convection.
- Relative humidity = vapour present ÷ maximum the air can hold at that temperature, as a %.
- Dew point = the temperature at which cooling air becomes saturated (100 % RH) and condensation begins.