Conduction
Vibrations passed particle to particle. Metals are best (free electrons).
Mechanism. In solids, particles vibrate. A heated end has particles vibrating MORE. They jostle their neighbours, who jostle theirs — vibration energy passes through.
In metals (Extended). A second mechanism dominates: free (delocalised) electrons. The electrons gain KE at the hot end and travel quickly to cooler regions, transferring energy with them. This is why metals conduct heat MUCH better than non-metals.
Order of conductors.
- Best: metals (especially copper, aluminium).
- Middling: other solids (glass, brick).
- Poor: liquids, then gases (very poor — particles too far apart).
- Worst: vacuum (no particles at all → no conduction).
Worked qualitative. Why does a metal handle on a saucepan get hot quickly, but a wooden one stays cool? Metal has free electrons → fast conduction. Wood has none → slow.
- Conduction: particle vibrations pass on energy.
- Metals: free electrons make it MUCH faster.
- Liquids and gases: poor conductors.
- Vacuum: no conduction at all.