Conduction
Heat travels through solids by particle vibration and (in metals) by free electrons.
Conduction: transfer of thermal energy through a material without bulk movement of the material itself.
Mechanism in non-metals:
- Hot particles vibrate more vigorously β pass energy to neighbouring particles by collision β energy spreads through solid
- Rate depends on how easily vibrations are transmitted
Mechanism in metals:
- In addition to particle vibration: free (delocalised) electrons carry thermal energy rapidly through the metal
- This is why metals are much better thermal conductors than non-metals
Thermal conductivity comparison:
| Material | Conductor/Insulator |
|---|---|
| Silver, copper, aluminium | Excellent conductors |
| Glass | Poor conductor |
| Wood | Insulator |
| Air | Very poor conductor / good insulator |
| Wool, expanded polystyrene | Good insulators (trap air) |
Factors affecting rate of conduction:
- Temperature difference (larger ΞT β faster conduction)
- Cross-sectional area of material (larger area β faster)
- Length/thickness (thicker material β slower)
- Material type (thermal conductivity)
Applications:
- Saucepan base: copper/aluminium (good conductor) β heats food quickly
- Handle: wood or plastic (poor conductor) β safe to touch
- Building insulation: fibreglass, rock wool, cavity walls (trap air) β slow heat loss
- Conduction in metals: free electrons carry energy + vibrations.
- Non-metals: vibration only β much slower conductors.
- Air is a poor conductor β insulating materials work by trapping air.