Metallic Bonding and Properties
Metals consist of positive ions in a sea of delocalised electrons. This structure explains all their key physical properties.
Metallic bonding: metal atoms release their outer electrons to form a 'sea' of delocalised electrons. The metal consists of a lattice of positive ions (cations) surrounded by and attracted to this electron sea.
Properties and explanations:
| Property | Explanation in terms of metallic bonding |
|---|---|
| Good conductors of electricity | Delocalised electrons are free to move through the lattice; carry charge |
| Good conductors of heat | Delocalised electrons transfer kinetic energy rapidly through the metal |
| Malleable and ductile | Layers of positive ions can slide past each other without breaking bonds (electron sea moves with them) |
| High melting and boiling points | Many strong electrostatic attractions between positive ions and electron sea require much energy to overcome |
| Shiny | Free electrons reflect light |
| Generally solid at room temperature | Strong metallic bonds (except Hg — liquid) |
Metals vs non-metals: Non-metals do NOT have delocalised electrons → poor conductors, brittle (bonds break when layers shift), low MP/BP (simple molecular).
Alloys:
- A mixture of metals (or metal + non-metal carbon/silicon)
- Different-sized atoms disrupt the regular lattice → layers cannot slide as easily → harder and stronger
- Examples: steel (Fe + C), brass (Cu + Zn), bronze (Cu + Sn), solder (Pb + Sn), amalgam (Hg + another metal)
- Steel is much harder than pure iron
- Metallic bond: cations in delocalised electron sea. Electrostatic attraction throughout.
- Delocalised electrons → conducts electricity + heat; malleable/ductile; shiny.
- Alloys: disrupted lattice → harder, stronger than pure metals.