Launching your learning experience…
Detailed notes on Atomic Physics for Cambridge IGCSE Coordinated Science, covering key concepts, explanations, examples, and exam-focused revision points.
The atom has a tiny, dense, positively charged nucleus containing protons and neutrons, with electrons orbiting in shells. Cambridge tests atomic structure, isotopes, nuclide notation, and the evidence from the Rutherford scattering experiment.
Mapped to the Cambridge IGCSE 0654 syllabus (2025-2027).
The atom is mostly empty space — a dense positive nucleus surrounded by orbiting electrons.
Structure of the atom:
| Particle | Relative mass | Relative charge | Location |
|---|---|---|---|
| Proton | 1 | +1 | Nucleus |
| Neutron | 1 | 0 | Nucleus |
| Electron | 1/1836 (≈ 0) | −1 | Shells around nucleus |
Key numbers:
Nuclide notation:
ᴬ_Z X
Isotopes:
Ions:
The Geiger-Marsden experiment disproved the plum pudding model and led to the nuclear atom model.
The plum pudding model (Thomson, 1904):
The Rutherford scattering experiment (Geiger and Marsden, ~1909):
Setup:
Results:
Conclusions (Rutherford's interpretation):
The nuclear model:
Scale: If an atom were the size of a football stadium, the nucleus would be the size of a grain of rice.
Verbatim phrases and definitions Cambridge mark schemes credit.
Paper 4: 'How many neutrons are in ⁵⁶₂₆Fe (iron-56)?' (1 mark — 56 − 26 = 30 neutrons). 'State what is meant by isotopes of an element' (2 marks — atoms with the same number of protons/atomic number but different number of neutrons/mass number). 'In the Rutherford scattering experiment, most alpha particles pass through the gold foil with little deflection. What does this tell us about the structure of the gold atom?' (2 marks — atom is mostly empty space; nucleus is very small). 'A small fraction of alpha particles are deflected by more than 90°. Explain this observation' (2 marks — nucleus is very small but dense and positively charged; alpha particles that pass very close to the nucleus are repelled by the strong positive charge).
Sources: Cambridge IGCSE Coordinated Sciences 0654 syllabus 2025-2027 (P8); 0654 Examiner Reports 2022-2024. Last reviewed 2026-05-14.
Step-by-step solutions to past-paper-style questions on the nuclear atom, written exactly the way a tutor would explain them at the board.
Question
A nuclide is written as 2656Fe. State (a) the atomic number, (b) the mass number, (c) the number of protons, (d) the number of neutrons, and (e) the number of electrons in a neutral atom.
Step-by-step solution
Step 1
The atomic number Z=26 (bottom number). This equals the number of protons.
Step 2
The mass number A=56 (top number). This equals the total number of nucleons (protons + neutrons).
Step 3
Number of neutrons: N=A−Z=56−26=30.
N=56−26=30
Step 4
In a neutral atom, number of electrons = number of protons = 26.
Answer
Z=26 (protons); A=56; neutrons =30; electrons =26.
Question
Describe the Geiger-Marsden (Rutherford) alpha-scattering experiment and explain what each observation revealed about atomic structure.
Step-by-step solution
Step 1
Setup: a beam of alpha particles was directed at a thin gold foil. A detector (zinc sulfide screen) surrounded the foil to detect alpha particles at all angles.
Step 2
Observation 1: Most alpha particles passed straight through without deflection. Conclusion: the atom is mostly empty space — most of the volume contains no significant matter.
Step 3
Observation 2: A small fraction of alpha particles were deflected through large angles (more than 90°), some almost straight back. Conclusion: there is a tiny, dense, positively charged nucleus at the centre. The positive charge of the nucleus repels the positive alpha particles.
Step 4
Conclusion: Atoms consist of a tiny, dense, positively charged nucleus surrounded by a large volume of empty space in which electrons orbit.
Answer
Most alphas: pass straight through (atom is mainly empty space). Some large deflections: tiny dense positive nucleus exists. Very few bounce back: nuclear diameter ≪ atomic diameter.
Examiner tip
Examiners reward explicit links between each observation and its conclusion. State both the observation AND what it proves.
Question
Carbon-12 (612C) and carbon-14 (614C) are isotopes. Explain what isotopes are and state how these two atoms are similar and how they differ.
Step-by-step solution
Step 1
Isotopes are atoms of the same element that have the same number of protons (atomic number) but different numbers of neutrons (and therefore different mass numbers).
Step 2
Similarities: both have 6 protons and 6 electrons. They have the same chemical properties because chemical behaviour is determined by the number of electrons (and hence protons).
Step 3
12C: 6 protons, 6 neutrons. 14C: 6 protons, 8 neutrons.
Step 4
Difference: different mass numbers (A=12 vs A=14) and different numbers of neutrons. They may also differ in nuclear stability — 14C is radioactive.
Answer
Isotopes: same Z (protons), different N (neutrons). Same chemical properties, different mass numbers. 12C: 6n; 14C: 8n.
The formulae you need to memorise for the nuclear atom on the Cambridge IGCSE 0654 paper, with every variable defined in plain English and a note on when to use it.
A=Z+N
When to use
Finding the number of neutrons when atomic number and mass number are given.
ZAX
When to use
Writing and interpreting the standard notation for any nuclide.
Definitions to memorise and the exact keywords mark schemes credit for the nuclear atom answers — sharpened from recent examiner reports for the 2026 0654 sitting.
A positively charged particle in the nucleus. Relative charge: +1; relative mass: 1. The number of protons (atomic number Z) defines which element the atom is.
An uncharged particle in the nucleus. Relative charge: 0; relative mass: 1. The number of neutrons can vary between atoms of the same element (isotopes).
A negatively charged particle orbiting the nucleus. Relative charge: −1; relative mass: ≈1/1836 (negligible). In a neutral atom, the number of electrons equals the number of protons.
Atoms of the same element (same atomic number Z) with different numbers of neutrons (different mass numbers A). Isotopes have identical chemical properties.
Example
92235U and 92238U are isotopes of uranium.
A collective term for protons and neutrons — the particles found in the nucleus. The mass number equals the total number of nucleons.
The traps other students keep falling into on the nuclear atom questions — taken from recent Cambridge IGCSE 0654 examiner reports and mark schemes — and how to avoid them.
Why it happens
Both are numbers associated with an atom; students do not remember which is on top and which is on the bottom in nuclide notation.
How to avoid it
In ZAX: A (top) = mass number (total nucleons); Z (bottom) = atomic number (protons). Neutrons =A−Z.
Why it happens
Students think 'different mass number → different everything'.
How to avoid it
Neutral atoms always have the same number of electrons as protons. Isotopes differ only in neutron number. Electron number is unchanged between isotopes of the same element.
Why it happens
Students mix up Thomson's plum-pudding model with Rutherford's nuclear model.
How to avoid it
Rutherford's experiment disproved the plum-pudding model. The nuclear model (tiny dense nucleus) was Rutherford's conclusion, not Thomson's.
The things students keep getting wrong in this sub-topic, answered.