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Detailed notes on Air and Water for Cambridge IGCSE Coordinated Science, covering key concepts, explanations, examples, and exam-focused revision points.
Water is an essential solvent and reactant. Cambridge tests water purification, properties of water, the water cycle, and tests for water (anhydrous copper sulfate and cobalt chloride paper).
Mapped to the Cambridge IGCSE 0654 syllabus (2025-2027).
Water is a polar molecule with unique properties — high boiling point (hydrogen bonding), universal solvent, and essential for life. Tests confirm the presence of water.
Tests for water:
Both tests confirm the PRESENCE of water — not that it is pure. Boiling/melting point confirms purity.
Properties of water:
Drinking water must be treated to remove solids and microorganisms. Hard water contains dissolved Ca²⁺/Mg²⁺ ions and requires softening.
Water treatment (to make safe drinking water):
This removes particles and microorganisms but NOT dissolved solutes. For pure water, distillation is required.
Hard water:
Temporary hardness (Ca(HCO₃)₂):
Ca²⁺ + 2HCO₃⁻ → CaCO₃ (scale) + H₂O + CO₂ on heating
Permanent hardness (CaSO₄, MgSO₄):
Soft water advantages: lathers easily, no limescale. Hard water advantages: Ca²⁺ good for teeth and bones; less corrosion of lead pipes.
Verbatim phrases and definitions Cambridge mark schemes credit.
Paper 4: 'Describe a chemical test to show that a liquid is water' (2 marks — anhydrous CuSO₄, turns blue; OR CoCl₂ paper, turns pink). 'Explain how temporary hardness of water differs from permanent hardness' (3 marks — temporary: Ca(HCO₃)₂, removed by boiling; permanent: CaSO₄, not removed by boiling). 'State THREE stages in treating river water to make it safe to drink' (3 marks — sedimentation, filtration, chlorination).
Sources: Cambridge IGCSE Coordinated Sciences 0654 syllabus 2025-2027 (C11); 0654 Examiner Reports 2022-2024. Last reviewed 2026-05-14.
Step-by-step solutions to past-paper-style questions on water, written exactly the way a tutor would explain them at the board.
Question
Describe a chemical test for the presence of water and state the expected result.
Step-by-step solution
Step 1
Test 1: add anhydrous copper(II) sulfate (white powder) to the unknown liquid.
CuSO4(white)+5H2O→CuSO4⋅5H2O(blue)
Step 2
Result: if water is present, the white anhydrous copper sulfate turns blue (forms hydrated CuSO₄·5H₂O).
Step 3
Alternative: use cobalt(II) chloride paper (blue when dry). Water turns it pink/red. This is a faster test but less specific.
Answer
Add anhydrous CuSO₄ (white): turns blue if water present. OR: cobalt chloride paper turns blue → pink in water.
Examiner tip
Both tests show the PRESENCE of water; to confirm it is pure water, also measure the boiling point (pure water = exactly 100 °C at 1 atm).
Question
Explain the difference between temporary and permanent hardness in water.
Step-by-step solution
Step 1
Temporary hardness: caused by dissolved calcium hydrogencarbonate (Ca(HCO₃)₂) or magnesium hydrogencarbonate. Removed by boiling.
Ca(HCO3)2(aq)→CaCO3(s)+H2O(l)+CO2(g)
Step 2
On boiling, Ca²⁺ ions are removed as insoluble CaCO₃ (limescale), softening the water.
Step 3
Permanent hardness: caused by dissolved calcium sulfate (CaSO₄) or magnesium chloride/sulfate. Cannot be removed by boiling.
Step 4
Permanent hardness is removed by: (a) ion exchange (replaces Ca²⁺/Mg²⁺ with Na⁺/H⁺); (b) adding sodium carbonate (Na₂CO₃): CO₃²⁻ precipitates Ca²⁺ as CaCO₃.
Answer
Temporary: Ca(HCO₃)₂/Mg(HCO₃)₂; removed by boiling → CaCO₃ precipitates. Permanent: CaSO₄/MgSO₄; NOT removed by boiling; removed by ion exchange or Na₂CO₃.
Examiner tip
Both methods of removing permanent hardness (ion exchange and Na₂CO₃) are equally acceptable.
Question
Explain why hard water forms a scum with soap, but softened water does not.
Step-by-step solution
Step 1
Hard water contains Ca²⁺ and Mg²⁺ ions.
Step 2
Soap contains sodium stearate (soluble). Ca²⁺ and Mg²⁺ ions react with stearate ions to form calcium/magnesium stearate, which is insoluble — this is the grey scum.
Step 3
In softened water, Ca²⁺ and Mg²⁺ ions have been removed (replaced by Na⁺); Na⁺ does not react with stearate ions to form a precipitate; soap lathers directly.
Answer
Ca²⁺/Mg²⁺ in hard water react with soap to form insoluble calcium/magnesium stearate (scum); softened water lacks these ions → soap forms lather directly.
Definitions to memorise and the exact keywords mark schemes credit for water answers — sharpened from recent examiner reports for the 2026 0654 sitting.
Water containing dissolved Ca²⁺ and/or Mg²⁺ ions (from dissolving limestone, chalk, or dolomite); does not lather readily with soap and forms scum.
Hardness caused by dissolved calcium hydrogencarbonate or magnesium hydrogencarbonate; removed by boiling (CaCO₃ precipitates, removing Ca²⁺ from solution).
Hardness caused by dissolved CaSO₄ or MgCl₂/MgSO₄; cannot be removed by boiling; removed by ion exchange or addition of Na₂CO₃.
A water-softening method in which Ca²⁺ and Mg²⁺ ions in hard water are replaced by Na⁺ or H⁺ ions as the water passes through a resin containing these ions.
A white deposit of calcium carbonate (CaCO₃) that forms in kettles, pipes, and boilers when water containing temporary hardness is heated; reduces heating efficiency.
Treatment of water for drinking: sedimentation (large particles settle), filtration (removes fine particles/bacteria through sand beds), chlorination (kills remaining bacteria).
The traps other students keep falling into on water questions — taken from recent Cambridge IGCSE 0654 examiner reports and mark schemes — and how to avoid them.
Why it happens
Students exaggerate the reason for preferring soft water.
How to avoid it
The reason is practical: soft water lathers easily with soap (no scum formation), not that Ca²⁺/Mg²⁺ are toxic. In fact Ca²⁺ is beneficial for teeth and bones.
0654 Examiner Report 2023
Why it happens
Students generalise the boiling method to all hard water types.
How to avoid it
Boiling only removes TEMPORARY hardness (Ca(HCO₃)₂ → CaCO₃ + CO₂ + H₂O). Permanent hardness (CaSO₄) is unaffected by boiling.
Why it happens
Students conclude identity from a positive result.
How to avoid it
These tests prove the PRESENCE of water, but the liquid could be an aqueous solution. To confirm it is PURE water, check the boiling point (100 °C) or freezing point (0 °C).
The things students keep getting wrong in this sub-topic, answered.