Question 1
Paper 4 short-answer style1 markState the relative charge of an electron. (1 mark)
Model answer
(a single negative charge).
Why this scores
One mark for . The proton is and the neutron is ; only the electron is negative.
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Detailed notes on Atoms, Elements and Compounds for Cambridge IGCSE Chemistry, covering key concepts, explanations, examples, and exam-focused revision points.
Protons, neutrons and electrons; proton number, nucleon number; electronic configurations; how electronic structure links to position on the Periodic Table.
Mapped to the Cambridge IGCSE 0620 syllabus (2026-2028).
Three particles: proton (+1), neutron (0), electron (-1). Use ZAX to identify a nuclide.
The three subatomic particles.
| Particle | Charge | Relative mass | Location |
|---|---|---|---|
| Proton | +1 | 1 | Nucleus |
| Neutron | 0 | 1 | Nucleus |
| Electron | −1 | ∼1/1836 | Shells around nucleus |
Atomic notation. ZAX
Number of each particle in a neutral atom.
Worked. 1327Al (aluminium-27).
Ion. An atom that has gained or lost electrons.
Worked. Mg²⁺ ion. Magnesium has Z=12.
Electrons fill shells from inside out: 2 in first, 8 in second, 8 in third (for elements 1-20).
Shell capacities (for the first 20 elements).
Filling order. Fill the lowest shell first, then move outwards.
Worked. Sodium (Z=11).
Worked. Chlorine (Z=17).
Worked. Calcium (Z=20).
Outer electrons (valence) determine reactivity. Group 1 (1 outer e⁻) and Group 17 (7 outer e⁻) are highly reactive. Group 18 (8 outer e⁻ — full shell) are inert (noble gases).
Drawing electronic structure. Cambridge accepts dot diagrams (concentric circles with × or • marks) — show the right number of electrons in each shell.
Period = number of shells. Group = number of outer electrons.
Period number = number of OCCUPIED shells.
Group number (for the main groups, 1-2 and 13-18) = number of OUTER-SHELL electrons.
Why the Periodic Table is the SHAPE it is. Elements in the same group have the SAME outer-shell configuration — that's why they have similar chemical properties. Sodium and potassium both have 1 outer electron → both react vigorously with water.
Worked. A neutral element has electronic configuration 2,8,6.
Cambridge tip. Most properties (atomic radius, ionisation energy, reactivity) follow trends DOWN groups and ACROSS periods. See the Periodic Trends study note for details.
Verbatim phrases and definitions Cambridge mark schemes credit.
Atomic structure appears every Paper 2 (4-5 marks: identify particles, write electronic configuration) and every Paper 4 (5-7 marks: link configuration to Periodic Table position, ions). Examiner reports flag confusing A with Z and forgetting that ions have a different number of electrons from the neutral atom.
Sources: Cambridge IGCSE Chemistry 0620 syllabus 2026-2028 (1.4); 0620/42 Oct/Nov 2024 — Q3 (electronic configurations); 0620 Examiner Reports 2022-2024. Last reviewed 2026-05-06.
Step-by-step solutions to past-paper-style questions on atomic structure and the periodic table, written exactly the way a tutor would explain them at the board.
Question
How many protons, neutrons and electrons are in 1123Na (neutral atom)?
Step-by-step solution
Step 1
The bottom number is the proton (atomic) number Z=11, so there are 11 protons.
Step 2
The top number is the nucleon (mass) number A=23. Neutrons =A−Z=23−11=12.
Step 3
An atom is neutral, so electrons = protons =11.
Answer
11 protons, 12 neutrons, 11 electrons.
Examiner tip
Neutrons are always A−Z, never A. The top number counts protons AND neutrons together.
Question
State the relative charge and relative mass of a proton, a neutron and an electron.
Step-by-step solution
Step 1
Proton: relative charge +1, relative mass 1. Found in the nucleus.
Step 2
Neutron: relative charge 0, relative mass 1. Also in the nucleus.
Step 3
Electron: relative charge −1, relative mass 18401 (≈ negligible). Found in shells around the nucleus.
Answer
Proton: +1, mass 1. Neutron: 0, mass 1. Electron: −1, mass 18401 (negligible).
Examiner tip
Because electrons have negligible mass, almost all of an atom's mass is in the nucleus (protons + neutrons).
Question
Write the electronic configuration of phosphorus, Z=15.
Step-by-step solution
Step 1
There are 15 electrons to place. Fill the inner shells first: shell 1 holds 2, shell 2 holds 8. That uses 10 electrons.
Step 2
Place the remaining 15−10=5 electrons in the third shell.
2,8,5
Answer
2,8,5
Examiner tip
Always check the digits sum to Z: 2+8+5=15. ✓
Question
An element has the electronic configuration 2,8,7. State its Group, its Period, and name it.
Step-by-step solution
Step 1
The number of outer-shell electrons gives the Group: 7 outer electrons → Group VII.
Step 2
The number of occupied shells gives the Period: 3 shells → Period 3.
Step 3
Total electrons =2+8+7=17=Z, so the element is chlorine.
Answer
Group VII, Period 3 — chlorine.
Examiner tip
Group = OUTER electrons only; Period = number of shells. Don't use the total electron count for the Group.
Question
Work out the numbers of protons, neutrons and electrons in the ion 1327Al3+.
Step-by-step solution
Step 1
Protons =Z=13 (the bottom number is unchanged by the charge).
Step 2
Neutrons =A−Z=27−13=14.
Step 3
A 3+ charge means the atom has lost 3 electrons: electrons =13−3=10.
Answer
13 protons, 14 neutrons, 10 electrons.
Examiner tip
Charge changes only the electron count. A positive ion has FEWER electrons than protons; a negative ion has MORE. The neutral atom Al has configuration 2,8,3.
Question
Element X has 19 electrons. Write its electronic configuration, give its Group and Period, and predict the charge of the ion it forms.
Step-by-step solution
Step 1
Fill the shells: 2, then 8, then 8 (the third shell takes 8 before the fourth starts in this simple model), leaving 1 for the fourth shell.
2,8,8,1
Step 2
Outer shell has 1 electron → Group I. There are 4 occupied shells → Period 4. (X is potassium, K.)
Step 3
A Group I metal loses its single outer electron to reach a stable noble-gas configuration, forming a 1+ ion.
Answer
2,8,8,1; Group I, Period 4; forms K+.
Examiner tip
For the first 20 elements the third shell is treated as holding 8 before the fourth begins, so K is 2,8,8,1 not 2,8,9.
High-scoring sample answers for atomic structure and the periodic table on the Cambridge IGCSE 0620 paper, with examiner-style notes mapping each response to the mark scheme and assessment objectives.
State the relative charge of an electron. (1 mark)
Model answer
−1 (a single negative charge).
Why this scores
One mark for −1. The proton is +1 and the neutron is 0; only the electron is negative.
An atom is represented as 1735Cl. State the number of protons and the number of neutrons in this atom. (2 marks)
Model answer
Protons =17 (the proton number Z). Neutrons =A−Z=35−17=18.
Why this scores
Two marks: one for 17 protons, one for 18 neutrons. The most common error is writing 35 neutrons — that is the total of protons AND neutrons.
An atom has 16 electrons. Write its electronic configuration and name the element. (3 marks)
Model answer
Fill the shells in order: 2 in the first, 8 in the second, leaving 6 for the third, giving 2,8,6. The total is 2+8+6=16, so the proton number is 16 — the element is sulfur.
Why this scores
Three marks: correct first/second shells (2,8); correct outer shell (6); correct element (sulfur). Check the digits add up to the electron number.
An element is in Group II and Period 3 of the Periodic Table. Deduce its electronic configuration and explain how you used its position to work it out. (4 marks)
Model answer
The Period tells you the number of occupied electron shells, so Period 3 means three shells. The Group tells you the number of outer-shell electrons, so Group II means two electrons in the outer shell. Filling the inner shells fully (2 then 8) and placing 2 in the third shell gives the configuration 2,8,2. (The element is magnesium.)
Why this scores
Four marks: Period → number of shells; Group → number of outer electrons; inner shells filled 2,8; final configuration 2,8,2. Stating the link in words is what scores the explanation marks.
Calculate the number of protons, neutrons and electrons in the ion 1224Mg2+. (5 marks)
Model answer
The proton number is 12, so there are 12 protons. The nucleon number is 24, so the number of neutrons is A−Z=24−12= 12 neutrons. A neutral magnesium atom would have 12 electrons, but the 2+ charge shows it has lost two electrons, so it has 12−2= 10 electrons. The lost electrons came from the outer shell, leaving the stable configuration 2,8.
Why this scores
Five marks: 12 protons; using A−Z; 12 neutrons; recognising a 2+ ion has lost 2 electrons; 10 electrons. The charge never changes the proton or neutron count.
Describe the structure of an atom, and explain why almost all of its mass is concentrated in the nucleus. (6 marks)
Model answer
An atom has a small, central nucleus that contains protons and neutrons. The electrons move around the nucleus in shells (energy levels). A proton has a relative charge of +1 and a relative mass of 1; a neutron has a relative charge of 0 and a relative mass of 1; an electron has a relative charge of −1 and a relative mass of only 18401, which is negligible. An atom is electrically neutral because the number of protons equals the number of electrons, so the positive and negative charges balance. Because the electrons have negligible mass, almost all of the atom's mass comes from the protons and neutrons in the nucleus, which is why the mass is concentrated there.
Why this scores
Six marks across: nucleus contains protons and neutrons; electrons in shells around it; relative charges (+1, 0, −1); relative masses (1, 1, 18401); atom neutral because protons = electrons; mass in nucleus because electron mass is negligible.
The formulae you need to memorise for atomic structure and the periodic table on the Cambridge IGCSE 0620 paper, with every variable defined in plain English and a note on when to use it.
ZAX
When to use
Reading off particle numbers: protons =Z, neutrons =A−Z, electrons =Z for a neutral atom.
2, 8, 8, 2
When to use
Building electronic configurations of H to Ca: shell 1 holds 2, shell 2 holds 8, shell 3 holds 8, then the fourth shell begins.
Definitions to memorise and the exact keywords mark schemes credit for atomic structure and the periodic table answers — sharpened from recent examiner reports for the 2026 0620 sitting.
The number of protons in the nucleus of an atom. It defines the element and (in a neutral atom) equals the number of electrons.
The total number of protons plus neutrons in the nucleus of an atom.
How the electrons of an atom are arranged in shells around the nucleus, e.g. 2,8,7 for chlorine.
A vertical column in the Periodic Table. Elements in the same Group have the same number of outer-shell electrons.
A horizontal row in the Periodic Table. Elements in the same Period have the same number of occupied electron shells.
The traps other students keep falling into on atomic structure and the periodic table questions — taken from recent Cambridge IGCSE 0620 examiner reports and mark schemes — and how to avoid them.
0620/42 — recurring
Why it happens
Two numbers sit close together in the nuclide symbol and look similar.
How to avoid it
Z is at the BOTTOM = protons. A is at the TOP = protons + neutrons. Neutrons =A−Z.
Why it happens
The top number is called the 'mass number', so students read it as the neutron count.
How to avoid it
Neutrons are always nucleon number MINUS proton number: neutrons =A−Z.
Why it happens
Forgetting the simple shell-capacity model for the first 20 elements.
How to avoid it
For H to Ca: shell 1 holds 2, shell 2 holds 8, shell 3 holds 8, then the fourth shell starts. So K is 2,8,8,1.
Why it happens
Students treat ions exactly like neutral atoms, or adjust the wrong particle.
How to avoid it
Charge changes ONLY electrons. Positive ion = fewer electrons (lost); negative ion = more electrons (gained). Protons and neutrons are unchanged.
The things students keep getting wrong in this sub-topic, answered.