Solubility rules
Memorise the soluble groups; everything else needs checking.
Always soluble.
- Group 1 metal salts (Li⁺, Na⁺, K⁺): always.
- Ammonium () salts: always.
- All NITRATES: always.
Mostly soluble (with exceptions).
- CHLORIDES: soluble EXCEPT silver () and lead ().
- SULFATES: soluble EXCEPT barium (), lead (), and calcium (sparingly).
Mostly insoluble (with exceptions).
- CARBONATES: insoluble EXCEPT Group 1 + ammonium.
- HYDROXIDES: insoluble EXCEPT Group 1 + ammonium + Ca(OH)₂ (sparingly).
- OXIDES: insoluble EXCEPT Group 1 metal oxides and CaO.
Worked example. Is sodium nitrate soluble? Yes — Group 1 + nitrate (both rules say soluble).
Worked example. Is silver chloride soluble? NO — silver is the chloride exception.
Worked example. Is iron(II) carbonate soluble? NO — carbonates are insoluble except Group 1/ammonium.
- Group 1 + ammonium: always soluble.
- Nitrates: always soluble.
- Chlorides: usually soluble (not Ag, Pb).
- Sulfates: usually soluble (not Ba, Pb).
- Carbonates / hydroxides / oxides: usually NOT soluble.